Conjugated Polymers: The Novel Science and Technology of by C. B. Gorman, R. H. Grubbs (auth.), J. L. Brédas, R. Silbey

By C. B. Gorman, R. H. Grubbs (auth.), J. L. Brédas, R. Silbey (eds.)

` The booklet should be obligatory studying for anyone offering towork within the sector and may be via a brief examination prior to a`practitioners licence' is issued.'
Chemistry & Industry
'This booklet is a steered addition to medical libraries and to scientists attracted to final abreast of modern advances....'Polymers News 17 1992

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Chem. Eng. News 1984, 28. ; Tamura, H. J. Chem. Soc. Chem. Commun. 1985,684. (50) Noufi, R. J. Electrochem. Soc. 1983, 130, 2126. (51) Bull, R. ; Bard, A. J. J. Electrochem. Soc. 1983, 130, 1636. ; Tamura, H. Chern. Lett. 1983, 1821. ; Techagumpuch, A. Synth. Met. 1989,31,311-318. ; Salaneck, W. R. Polymer 1990, 31, 395-399. (55) MacDiarmid, A. ; Epstein, A. J. J. Chem. Soc. Faraday Discuss. 1989, 88, 317-332. ; Epstein, A. J. J. Am. Chem. Soc. 1990, 112, 2800-2801. (57) Diaz, A. ; Logan, J. A.

Graphite, a cheap, common organic material can be doped with AsPs to a conductivity of approx. 354 Potassium-doped graphite superconducts at low temperatures. 35S These examples are simple practical realizations of the properties that drive much of this search and are described here to encourage researchers to be critical of the different synthetic techniques and aware of possible structural variations in these materials rather than accepting the structure that is drawn on paper. More structural control in the synthesis of materials and acknowledgement of structural flaws in materials should result in a quicker and more correct understanding of their physics and chemistry.

This heteroatom, in addition to fixing the geometry of some of the bonds in the polymer, influences the electronic structure of the polymer. The changes in properties corresponding upon structural variation have been explained in a very intuitive way using orbital-mixing arguments,130,131 There. continues to be a synthetic challenge in the further variation of the heteroatom. 132 Me Me Me Me Figure 16. A first step toward the phosphorous analogues of polythiophenes. 25. Polyparaphenylene (PPP).

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