Colloid Chemistry I by Antonietti M.

By Antonietti M.

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13). Again, the structure of the resulting inorganic nanostructure depends on that of the parental LLC phase; accordingly a lamellar nanostructure was obtained from a lamellar phase, an hexagonal one from a hexagonal phase and hollow spheres from a micellar cubic phase. Fig. 13. TEM image of hexagonally structured cadmium sulfide Nanocasting of Lyotropic Liquid Crystal Phases for Metals and Ceramics 47 The same procedure was applied to the synthesis of cadmium selenide and zinc sulfide in LLC surfactant phases using CnEOm surfactants.

3 Precipitation in LLC Phases . . . . . . . . . . . 2 Precipitation of Semiconductor Particles . . . . . . . . 46 Chemical Reduction of Noble Metal Salts . . . . . . . . 2 Noble Metal-Containing LLC Phases . . . . . . . . . 49 Electrochemical Reduction of Metal Salts . . . . . . . 49 5 Summary and Outlook . . . . . . . . . . . . . 52 6 References . . . . . . . . . . . . . . . . 53 . . . . . . . . . . . . . . . .

53 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 33 35 36 40 42 44 . 49 © Springer-Verlag Berlin Heidelberg 2003 30 C. 1 Structure of Surfactant Phases Amphiphilic molecules, such as surfactants or amphiphilic block copolymers (ABCs), are compounds in which a hydrophilic and a hydrophobic component are linked covalently. All these aggregates form without external manipulation by processes of supramolecular selfassembly.

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