Advances in Molecular Structure Research, Volume 1 by Magdolna Hargittai (Editor), Istvan Hargittai (Editor)

By Magdolna Hargittai (Editor), Istvan Hargittai (Editor)

Development in molecular constitution study displays development in chemistry in lots of methods. a lot of it's therefore mixed inseparably with the remainder of chemistry. it sounds as if to be prudent, despite the fact that, to study the frontiers of this box at times. this can support the structural chemist to delineate the most thrusts of advances during this sector of analysis. what's much more very important even though, those efforts may well support the remainder of the chemists to benefit approximately new chances in structural reviews, either methodological and interpretation. the purpose is to make this a user-oriented sequence. Structural chemists of excellence could be seriously comparing a box or course together with their very own achievements, and charting anticipated advancements.

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We are aiming at the broadest coverage of structural chemistry over the years in this and future volumes. iil. L O O K I N G BACK Perspectives mean not only the future but the past as well. We find it prudent to review the origins of structural considerations in chemistry. Here, however, we are going to mention only a few important moments without any attempt to be comprehensive. We have already quoted Kepler [3(b)] who first considered packing as he was examining the beautiful snow crystals. The atomistic views date back, of course, to the Greek philosophers of whom Democritos (460-370 B.

42 Chemical Shape . . . . . . . . . . . . . . . . . 46 VI. Intramolecular Interactions . . . . . . . . . . . . . . 46 VII. Intermolecular Interactions . . . . . . . . . . . . . . 53 . . . . . . . . . . . . . . . . 55 VIII. IX. Crystal Engineering Supramolecular Structures . . . . . . . . . . . . . . . 58 Note . . . . . . . . . . . . . . . . . . . . 58 References . . . . . . . . . . . . . .

58 Advances in Molecular Structure Research Volume 1, pages 33-61. Copyright 9 1995 by JAI Press Inc. All rights of reproduction in any form reserved. ISBN: 1-55938-799-8 33 34 ISTV,g,N HARGITTAI and MAGDOLNA HARGITTAI ABSTRACT Over the past years the accuracy of molecular structure determination has increased. This is due not only to improved experimental and computational facilities, and to the combined application of various techniques, but also to a better understanding of the physical meaning of structural information from different sources.

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