Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

By Krzysztof Matyjaszewski

Provides new advancements in controlled/living radical polymerization in 3 parts: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally contains synthesis and characterization of many new materials.

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Sci. : Polym. 2001,39, 1353. Monteiro, M . ; de Brouwer, H. Macromolecules 2001, 34, 349. Kwak, Y . ; Tsujii, Y . ; Murata, Y . ; Fukuda, T. Macromolecules 2002, 35, 3026. Kwak, Y . , to be published. Hui, A. ; Hamielec, A. E. J. Appl. Polym. 19 72, 16, 749. Molnar, S. J. Polym. , Part A-1 1972,10 , 2245. Gilbert, R. G. Pure Appl. Chem. 1996,68 , 1491. ; Fukuda, T. Macromol. Chem. Phys. 2000, 201, 2138. Ohno, K . ; Matyjaszewski, K . Macromolecules 1998, 31, 2699. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2003.

An initial plateau region of constant k is seen which, with M M A , extends up to about 20 % monomer conversion and is followed by a reduction inktby about three orders of magnitude up to 50 % conversion. Dodecyl acrylate (DA) shows a distinctly different behavior in that constant (plateau) kt is observed up to 75 % conversion. Copolymerization kt in the plateau region is adequately described by a penultimate unit effect model. The chain-length dependence of k is investigated for several homopolymerizations using the expression: kt = k .

16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. (a) Ohno, Κ. Tsujii, Y . ; Miyamoto, T. ; Kobayashi, K . Akaike, T. Macromolecules 1998, 31, 1064. ; Boutevin, B . Macromol Rapid Commun 2001, 22, 189. ; Boutevin, B . ; Fischer, H . ACS Symp. Ser. 2000, 768, 108. ; Fukuda, T. Macromolecules 2002, 353, 5081. ; Tsujii, Y . ACS Symp. Ser. This Volume. (a) Ananchenko, G . ; Fischer, H . J. Polym. Sci. : Polym. Chem. 2001, 39, 3604. (b) Ananchenko, G . ; Fischer, H . ; Tordo, P. J. Polym. Sci. : Polym. Chem.

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