Activation and Catalytic Reactions of Saturated Hydrocarbons by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

This monograph is dedicated to the activation and diverse variations of saturated hydrocarbons (alkanes), i.e. reactions followed via the C--H and C--C bond cleavage. Alkanes are the most parts of oil and traditional gasoline, and as a result are the significant feedstocks for the chemical undefined. nevertheless, those components are recognized to be the least reactive natural compounds. particular cognizance is paid to the lately chanced on alkane activations in the presence of steel complexes, that are defined in additional element. as well as the reactions of saturated hydrocarbons that are the major subject of this booklet, the activation of C--H bonds in arenes or even olefins and acetylenes are thought of. The monograph could be priceless not just should you have an interest in the activation of alkanes and different hydrocarbons through steel complexes, but in addition for experts in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. a few elements of the monograph could be of curiosity for experts in inorganic and natural chemistry, theoretical chemistry, biochemistry or even biology, and additionally in case you paintings within the petrochemical undefined, business natural synthesis and biotechnology.

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Shilov, A. E. J. Chem. , Chem. Commun. 1983, 671. Tyurina, L. ; Kombarova, S. ; Smirnov, V. V. Dokl. Akad. Nauk SSSR 1989, 309, 122 (in Russian). (a) Kharash, M. ; Isbell, H. C. J. Am. Chem. Soc. 1931, 53, 3053. ; Willstätter, R. Ber. 1931, 64B, 2844. (c) Milas, N. ; Sussman, S. J. Am. Chem. Soc. 1936, 58, 1302. (a) Kleiman, J. ; J. Am. Chem. Soc. 1963, 85, 1544. ; Davidson, J. M. J. Chem. Soc.. 1965, 843. ; Verberg, G. Recl. Trav. Chim. Pays-Bas 1965, 84, 1263. ; Danno, S. et al. J. Am. Chem.

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Khim. 1989, 2, 249 (in Russian). (d) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95. (e) Crabtree, R. H. Angew. , Int. Ed. Engl. 1993, 32, 789. (f) Heinekey, D. ; Oldham, W. , Jr. Chem. Rev. 1993, 93, 913. ; Perutz, R. N. Chem. Rev. 1996, 96, 3125. 3. 4. 5. 6. 7. 8. 9. (a) Sykes, P. A Guidebook to Mechanism in Organic Chemistry; Longman: London, 1971, Ch. 6. (b) Dneprovskiy, A. ; Temnikova, T. I. Theoretical Principles of Organic Chemistry, Khimiya: Leningrad, 1979, Chpts. 14, 15 (in Russian). (a) Taqui Khan, M.

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